Kapok fiber-supported liquid extraction for convenient oil samples preparations: A feasibility and proof-of-concept study
【作者】 Chen, Di; Wang, Bin; Xu, Xin-Li; Zhang, Man-Yu; Bu, Xin-Miao; Yang, Sen; Luo, Yanbo*; Xu, Xia*
【期刊名】 Journal of Chromatography A
【影响因子】 2021年: 4.601
【作者单位】 Key Laboratory of Targeting Therapy and Diagnosis for Critical Diseases of Henan Province, School of Pharmaceutical Sciences, Zhengzhou University, 100 Kexue Avenue, Zhengzhou 450001, PR China
【年，卷(期)：页码】2022, 1681: 463480
【关键词】 Kapok fiber-supported liquid extraction; Synthetic flavor chemicals; Edible oil; Determination; HPLC
【摘要】In this study, a novel kapok fiber-supported liquid extraction (KF-SLE) method was developed for conveniently extracting analytes from oil samples. Natural kapok fiber without any pretreatment was directly used as an oil support medium. The extraction device was conveniently constructed by directly packing some kapok fibers into a syringe tube. Due to the fibrous property of the kapok fiber, no filter plate was needed. The cost of a KF-SLE device was as low as 0.5 CNY. The KF-SLE process was conveniently conducted using a simple three-step protocol: (1) the oil sample without any pretreatment including dilution was added directedly; (2) then, the oil-immiscible extractant was added; (3) after waiting a certain time for static extraction, the extractant was eluted out by pressing the kapok fibers with the syringe plunger. The extractant could be directly transferred for subsequent instrumental detection. For the feasibility and proof-of-concept study, the method was applied to quantify four synthetic flavor chemicals in edible oils. Satisfied quantification results were obtained with the correlation coefficient (R2) being greater than 0.996, the relative recoveries ranging from 92.90% to 107.53% and intra- and inter-day RSDs being less than 7.56%. All in all, for the first time, the SLE technique was expanded to process oil samples and the method has the characteristics of low cost, environmental friendliness, high sample processing throughput and ease of automation, offering a promising approach for edible oil sample preparations.
【全文链接】
https://doi.org/10.1016/j.chroma.2022.463480
