姓 名:涂维峰
职 称:教授
地 址:郑州大学化工学院
邮 箱:weifengtu@zzu.edu.cn
教育与科研经历
2021.01-至今 郑州大学化工学院,教授
2018.01-2020.12 郑州大学化工学院,副教授
2016.01-2017.12 郑州大学化工与能源学院,讲师
2014.01-2016.12 加拿大多伦多大学,化学工程与应用化学,博士后
2009.09-2013.12 重庆大学动力工程学院动力工程及工程热物理博士研究生
2011.10-2013.10 加拿大多伦多大学联合培养博士研究生(国外2年)
2005.10-2009.07 重庆大学动力工程学院热能与动力工程工学学士
学术头衔/兼职
担任先进功能材料制造教育部工程研究中心副主任;中国化工学会过程强化专业委员会青年委员;《Catalysts》客座编辑、《天然气化工-C1化学与化工》期刊青年编委。
研究领域/方向
(1) CO、CO2催化加氢高值转化关键基础及技术研究;(2) 工业有机高盐废水深度处理技术研究;(3) 工业催化剂动态构效关系研究;(4) 催化反应机理及动力学研究;
主要结合反应动力学、同位素、化学滴定、光谱技术、密度泛函理论等策略,致力于从分子、原子尺度揭示多相催化反应的催化原理,剖析催化剂表界面结构及其动态演变机制,解析表面催化反应动力学及反应路径,构建催化剂表界面状态与催化反应动力学的关联机制,探索催化反应活性的周期性规律。研究工作聚焦表面吸附物诱导活性中心的形成机理及其催化作用。
代表性论文
[1] Shaokang Zhang, Hong Ma, Lingyu Jia, Zhenzhou Zhang*, Xinli Li, Shanshan Dang, Yanqiang Huang, Weifeng Tu*, Yi-Fan Han*, Nanostructure of Indium-driven nickel catalysts break CO2 hydrogenation preference, Applied Catalysis B: Environment and Energy, 2024,(accepted)
[2] Wenqi Liu, Shanshan Dang, Sifan Cheng, Zhenzhou Zhang, Xiaoya Ding, Yanling Shi, Pengchao Ren, Weifeng Tu*, and Yi-Fan Han*, Revealing the Interaction between Cu and MgO in Cu/MgO Catalysts for CO Hydrogenation to CH3OH. ACS Catalysis. 2024, 14, 7097–7110.
[3] Yanjia Guo, Lingyu Jia, Zhenzhou Zhang, Mengze Gong, Shanshan Dang, Yanqiang Huang, Xinhua Gao, Weifeng Tu*, Yi-Fan Han*. Revealing the mechanism of Ce promoter in modulating product distribution of CO2 hydrogenation over Fe-based catalysts. Chemical Engineering Journal, 2024, 491, 151964.
[4] Weifeng Tu, Pengchao Ren, Yuanjie Li, Yongpeng Yang, Yun Tian, Zhenzhou Zhang, Minghui Zhu, Ya-Huei Cathy Chin, Jinlong Gong*, Yi-Fan Han*, Gas-Dependent Active Sites on Cu/ZnO Clusters for CH3OH Synthesis, Journal of the American Chemical Society, 2023, 145(16), 8751-8756.
[5] Zhenzhou Zhang, Baojian Chen, Lingyu Jia, Wenqi Liu, Xinhua Gao, Jian Gao, Bo Meng, Yisheng Tan, Yurong He*, Weifeng Tu*, Yi-Fan Han*, "Unraveling the role of Fe5C2 in CH4 formation during CO2 hydrogenation over hydrophobic iron catalysts. Applied Catalysis B: Environmenta, 2023, 327, 122449.
[6] Zhenzhou Zhang, Sifan Cheng, Wenqi Liu, Baojian Chen, Xinhua Gao, Peng Wang, Jian Gao, Yisheng Tan, Shanshan Dang, Weifeng Tu*. Unraveling the regulation of Mn in Cu-ZnOx formation during methanol synthesis from syngas over Cu/ZnO/Al2O3-Mn catalysts. Applied Catalysis B: Environmental, 2023, 338(1), 122985.
[7] Haripal Singh Malhi, Zhenzhou Zhang, Yanling Shi, Xinhua Gao, Wenqi Liu, Weifeng Tu*, Yi-Fan Han*. The promotional effects of carbon nanotube on Fe5C2-ZnO catalysts for CO2 hydrogenation to heavy olefins. Fuel, 2023, 339, 127267.
[8] Haripal Singh Malhi#, Chao Sun#, Zhenzhou Zhang, Yangyang liu, Wenqi Liu, Pengchao Ren, Weifeng Tu*, Yi-Fan Han*,Catalytic consequences of the decoration of sodium and zinc atoms during CO2 hydrogenation to olefins over Iron-based Catalyst. Catalysis Today, 2022, 387, 28-37.
[9] Pengchao Ren1, Weifeng Tu1, Chanchan Wang, Sifan Cheng, Wenqi Liu, Zhenzhou Zhang, Yun Tian, Yi-Fan Han*, Mechanism and sites requirement for CO hydrogenation to CH3OH over Cu/CeO2 catalysts. Applied Catalysis B: Environmental, 2022, 305, 121016.
[10] Zhenzhou Zhang*, Yangyang Liu, Lingyu Jia*, Chao Sun, Baojian Chen, Rui Liu, Yisheng Tan, Weifeng Tu*, Effects of the reducing gas atmosphere on performance of FeCeNa catalyst for the hydrogenation of CO2 to olefins. Chemical Engineering Journal, 2022, 428, 131388.
[11] Yangyang Liu, Baojian Chen, Rui Liu, Wenqi Liu, Xinhua Gao, Yisheng Tan, Zhenzhou Zhang, Weifeng Tu*. CO2 hydrogenation to olefins on supported iron catalysts: Effects of support properties on carbon-containing species and product distribution. Fuel, 2022, 324(1), 124649.
[12] Wenqi Liu, Sifan Cheng, Haripal Singh Malhi, Xinhua Gao, Zhenzhou Zhang* and Weifeng Tu*. Hydrogenation of CO2 to Olefifins over Iron-Based Catalysts: A Review. Catalysts 2022, 12 (11), 1432.
[13] Weifeng Tu, Chao Sun, Zhenzhou Zhang, Wenqi Liu, Haripal Singh Malhi, Wei Ma, Minghui Zhu, Yi-Fan Han*, Chemical and structural properties of Na decorated Fe5C2-ZnO catalysts during hydrogenation of CO2 to linear α-olefins. Applied Catalysis B: Environmental, 2021, 298, 120567.
[14] Zhenzhou Zhang, Chongyang Wei, Lingyu Jia, Yangyang Liu, Chao Sun, Peng Wang, Weifeng Tu*, Insights into the regulation of FeNa catalysts modified by Mn promoter and their tuning effect on the hydrogenation of CO2 to light olefins, Journal of Catalysis, 2020, 390, 12-22.
[15] Chongyang Wei#, Weifeng Tu#, Lingyu Jia, Yangyang Liu, Honglei Lian, Peng Wang, Zhenzhou Zhang, The evolutions of carbon and iron species modified by Na and their tuning effect on the hydrogenation of CO2 to olefins, Applied Surface Science, 2020, 525, 146622-146634.
[16] Weifeng Tu, Yi-Fan Han, et.al., Catalytic Consequences of the Identity of Surface Reactive Intermediates during Direct Hydrogen Peroxide Formation on Pd Particles. Journal of Catalysis, 2019, 377: 494-506.
[17] Weifeng Tu, Mireille Ghoussoub, Chandra Veer Singh, and Ya-Huei (Cathy) Chin. Consequences of Surface Oxophilicity of Ni, Ni-Co, and Co Clusters on Methane Activation. Journal of the American Chemical Society, 2017, 139(20): 6928-6945 (一区SCI,影响因子:13.038).
[18] Weifeng Tu, Ya-Huei (Cathy) Chin. Catalytic Consequences of the Thermodynamic Activities at Metal Cluster Surfaces and their Periodic Reactivity Trend for Methanol Oxidation. Angewandte Chemie International Edition, 2014, 53: 12148-12152.(一区SCI,影响因子:13.7).
[19] Weifeng Tu, Ya-Huei (Cathy) Chin. Catalytic Consequences of Chemisorbed Oxygen during Methanol Oxidative Dehydrogenation on Pd Clusters. ACS Catalysis, 2015, 5:3375-3386(一区SCI,影响因子7.5).
[20] Weifeng Tu, Ya-Huei (Cathy) Chin. Catalytic Consequences of the Identity and Coverages of Reactive Intermediates during Methanol Partial Oxidation on Pt Clusters. Journal of Catalysis, 2014, 313: 55-69.(一区SCI,影响因子:6.0).
代表性专利
[1] 涂维峰, 时彦玲, 韩一帆. 一种吸附测试方法和装置, 中国授权发明专利, ZL 201711103129.5.
[2] 涂维峰, 时彦玲, 韩一帆, 王仁铨, 窦竞, 陈高翔. 固定床反应器, 中国授权发明专利,ZL 201810765655.6.
主持科研项目情况
[1] 国家自然科学基金, 面上项目,CO2 甲烷化环境诱导 Ni 基催化剂动态活性结构与反应机理研究,22278379,2023.01-2026.12,54万元
[2] 河南省科技研发计划联合基金, 优势学科联合基金重点项目,低温甲烷化镍基催化剂结构调控及催化反应机理研究,222301420010,2023.01-2025.12,80万元,
[3] 河南省自然科学基金, 优秀青年科学基金项目,COx 催化加氢制直链α烯烃反应过程原位动态解析与调控,232300421090,2023.01-2025.12,25万元
[4] 国家自然科学基金委员会,面上项目,22078307,铁基催化剂二氧化碳加氢制烯烃反应机制及反应动力学研究,2021.01-2024.12,64万元
[5] 郑州大学青年教师基础研究培育项目,JC202019017,铁基催化剂二氧化碳加氢的反应机制及反应动力学研究,2020.08-2021.12,20万元
[6] 郑州大学青年骨干教师培养项目,2018ZDGGJS039,煤基合成气制低碳醇机理及催化剂研究,2019.01-2021.12
[7] 国家自然科学基金委员会,青年科学基金项目,21606208, 贵金属催化剂催化氢氧直接合成过氧化氢的反应本征动力学及机理研究,2017-01至2019-12,20万元
[8] 郑州大学优秀教师发展基金,F0000987,合成气制低碳醇的催化反应动力学及机理研究,2017.01-2019.12,30万元
[9] 低品位能源利用技术及系统教育部重点实验室开放基金,LLEUTS-201707,微细通道内钯基催化剂上甲醇催化燃烧反应动力学及机理研究,2017.01-2018.12