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高其龙

高其龙

作者:暂无 时间:2025-02-05 点击数:




高其龙,学科特聘教授,博士生导师,河南省优青、杰青。


目前主持国家自然科学基金青年一项和面上两项,主持河南省自然科学基金优青项目和一项联合基金,主持中国博士后面上基金一项。近5年发表SCI论文60篇,其中以第一作者或通讯作者身份发表43篇SCI论文在J.Am.Chem.Soc.、Angew.Chem.Int.Ed.、Nat.Commun、Sci. China Matter.、Nano Research、Scripta. Matter.、Inorg.Chem.、Appl.Phys.Lett.等学术期刊。申请国家发明专利10项、授权4项。担任中国晶体学会局域结构专业委员会委员、担任期刊《Tungsten》、《Microstructure》和《Progress in Natural Science: Material International》青年编委,担任期刊《Rare Metal》Guest Editor,获得《Microstructure》2023年最佳青年编委。多次受邀在相关国际/国内大会上做邀请报告。

目前主要进行负热膨胀材料结构设计与机制以及负热膨胀引起的荧光热增强机制研究。利用同步辐射、中子散射等大装置开展研究(美国APS、NIST,英国ISIS,日本Spring-8,意大利Elettra等):设计“平均原子晶格体积”新概念为探索新NTE体系提供新方法,被JACS Spotlight重点推介;设计客体嵌入热膨胀的调控新方法,被期刊Angew编辑推荐为Hot paper,被意大利ELETTRA光源官网报道,并收录于年度ELETTRA Highlights和ESRF Highlights。通过对ZrV2O7结构设计实现其NTE温区延伸到室温以下,被APL选为Feature Article,并被美国物理学联合会AIP Scilight专访报道;提出超轻负热膨胀(Ultralight NTE)概念,发现NaB(CN)4巨负膨胀材料。

邮箱:qilonggao@zzu.edu.cn 

详细如下:

(一)教育经历

12013-92019-1,北京科技大学

22009-92013-7,辽宁科技大学

(二)科研和学术工作经历

12020-1至现在,郑州大学,物理学院,副教授,学科特聘教授

22019-12019-12,郑州大学,物理工程学院,讲师

(三)主持科研项目情况

1)国家自然科学面上基金,2021-012024-12

2)国家自然科学面上基金,2025-012028-12

3)国家自然科学青年基金,2020-012022-12

4)中国博士后科学基金面上资助,2019.05-2020.12

5)河南省自然科学基金,优青项目,2021-12023-12

6)河南省自然科学基金,杰青项目,2025-12027-12

7)河南省省级科技研发计划联合基金(优势学科培育类)2022-62024-6


(四)学术论文(第一/通讯,部分中科院分区1区以上)

1 Qilong Gao* , Yixin Jiao, Jan A. P. Sprenger, Maik Finze, Andrea Sanson, Qiang Sun, Erjun Liang, Jun Chen* Critical Role of Non-rigid unit and Spiral Acoustical Modes in Designing Colossal Negative Thermal Expansion. Journal of the American Chemical Society, 2024, 146, 2171021720


2Qilong Gao,* Yixin Jiao, Qiang Sun,* Jan A. P. Sprenger, Maik Finze, Andrea Sanson, Erjun Liang, Xianran Xing, and Jun Chen*. Giant Negative Thermal Expansion in Ultralight NaB(CN)4. Angewandte Chemie International Edition 2024, 63, e2024013.

(3) Qilong Gao, Jiaqi Wang, Andrea Sanson, Qiang Sun, Erjun Liang*, Xianran Xing, Jun Chen*. Discovering large isotropic negative thermal expansion in framework compound AgB(CN)4 via the concept of average atomic volume. Journal of the American Chemical Society, 2020, 142, 6935−6939.

(4) Qilong Gao, Jun Chen*, Qiang Sun, Dahu Chang, Qingzhen Huang, Hui Wu, Andrea Sanson, Ruggero Milazzo, He Zhu, Qiang Li, Zhanning Liu, Jinxia Deng and Xianran Xing. Switching between giant positive and negative thermal expansions of a YFe(CN)6-based Prussian blue analogue induced by guest species. Angewandte Chemie International Edition, 2017, 56, 9023−9028.

(5) Jun Chen, Qilong Gao, Andrea Sanson, Xingxing Jiang, Qingzhen Huang, Alberto Carnera, Clara Guglieri Rodriguez, Luca Olivi, Lei Wang, Lei Hu, Kun Lin, Yang Ren, Zheshuai. Lin, Cong Wang, Lin Gu, Jinxia Deng, J.P. Attfield* and Xingran Xing*. Tunable thermal expansion in framework materials through redox intercalation. Nature Communications, 2017, 8, 14441.

6Qingjie Wang, Yongqiang Qiao*, Kaiyue Zhao, Peixian Zhang, Huan Zhao, Juan Guo, Xinwei Shi*, Erjun Liang, Qilong Gao*. Zero thermal expansion in KxMnxIn2-x(MoO4)3 based materials. Acta Materialia 281 (2024) 120358

(7) Huan Zhao, Yongqiang Qiao, Kaiyue Zhao, Qingjie Wang, Peixian Zhang, Juan Guo, Mingju Chao, Erjun Liang, and Qilong Gao* Negative Thermal Expansion in ABC(MoO4)3 Compounds. Small 2024, 2403000

(8)Peixian Zhang, Yongqiang Qiao1, Kaiyue Zhao, Qingjie Wang, Huan Zhao, Juan Guo, Erjun Liang, Tao Sun, Jiangwei Zhang*, and Qilong Gao*. Synthesis, structure, and thermal expansion in CaZrF6 with two polymorphs. Nano Research 2024, 17, 8618-8626.

(9)Yongqiang Qiao, Irfan Liaquat, Yuhao Zhu, Juan Guo, Erjun Liang, and Qilong Gao*. Tunable thermal expansion via the magnetic phase competition in kagome magnets. Applied Physics Letters 2024, 125, 032403.

(10) Qilong Gao*, Qiang Sun, Alessandro Venier, Andrea Sanson, Qingzhen Huang, Yu Jia, Erjun liang and Jun Chen*. The role of average atomic volume in predicting negative thermal expansion: The case of REFe(CN)6. Science China Materials, 2022, 65, 553–557.

(11) QilongGao*, Sen Zhang, Yixin Jiao, Yongqiang Qiao*, Andrea Sanson, Qiang Sun, Xinwei Shi*, Erjun Liang and Jun Chen. A new isotropic negative thermal expansion material of CaSnF6 with facile and low-cost synthesis. Nano Research. 2023, 16, 5964-5972.

12Yongqiang Qiao, Sen Zhang, Peixian Zhang, Juan Guo, Andrea Sanson, Xi Zhen, Kaiyue Zhao, Qilong Gao,*, and Jun Chen*. Simple chemical synthesis and isotropic negative thermal expansion in MHfF6 (M = Ca, Mn, Fe, and Co). Nano Research 2024, 17(3): 2195−2203.

(13) Xi Zhen, Andrea Sanson, Qiang Sun*, Erjun Liang, and Qilong Gao*. Role of alkali ions in the near-zero thermal expansion of NaSICON-type AZr2(PO4)3 (A=Na, K, Rb, Cs) and Zr2(PO4)3 compounds. Physical Review B  2023,108, 144102.

(14) Kaiyue Zhao, Yixin Jiao, Qiang Sun,* Ri He,* Andrea Sanson, Zhicheng Zhong, Erjun Liang, Qilong Gao* Octahedral tilt distortion in the Negative Thermal Expansion fluorides of CaZrF6 and ScF3. Physical Review B  2024, 110, 064322.

(15) Ran Chen, Qilong Gao*, Yongqiang Qiao, Juan Guo and Erjun Liang*. Continuous tailoring thermal expansion from giant negative to positive in Ni2P2O7-based materials. Scripta Materialia, 2022, 214, 114653.

(16) Qilong Gao, Yu Sun, Naike Shi, Ruggero Milazzo, Simone Pollastri, Luca Olivi, Qingzhen Huang, Hui Liu, Andrea Sanson*, Qiang Sun*, Erjun Liang, Xianran Xing and Jun Chen*. Large isotropic negative thermal expansion in water-free Prussian blue analogues of ScCo(CN)6. Scripta Materialia, 2020, 187, 119−124.

(17) Qilong Gao, Xinwei Shi, Alessandro Venier, Alberto Carnera, Qingzhen Huang, Jun Chen*, Andrea Sanson*, Erjun Liang* Effect of H2O molecules on thermal expansion of TiCo(CN)6. Inorganic Chemistry, 2020, 59, 14852−14855.

(18) Huanli. Yuan, Chunyan. Wang, Qilong Gao*, Xianghong. Ge, Hao. Sun, Saul. H. Lapidus, Juan. Guo, Mingju. Chao, Yu. Jia and Erjun Liang*. Structure and negative thermal expansion in Zr0.3Sc1.7Mo2.7V0.3O12. Inorganic Chemistry, 2020, 59, 4090−4095.

(19) Qilong Gao, Naike Shi, Qiang Sun, Andrea Sanson, Ruggero Milazzo, Alberto, Carnera, He Zhu, Saul. H. Lapidus, Yang. Ren, Qingzhen Huang, Jun Chen*and Xianran Xing. Low-frequency phonon driven negative thermal expansion in cubic GaFe(CN)6 Prussian blue analogues. Inorganic Chemistry, 2018, 57, 10918–10924.

(20) Qilong Gao, Naike, Shi, Andrea Sanson, Yu. Sun, Ruggero. Milazzo, Luca, Olivi, He Zhu, Saul. H. Lapidus, Lirong Zheng, Jun Chen*, and Xianran Xing. Tunable thermal expansion from negative, zero, to positive in cubic Prussian blue analogues of GaFe(CN)6. Inorganic Chemistry, 2018, 57, 14027–14030.

(21) Yan Luo, Yongqiang Qiao,* Qilong Gao*, Jiaqi Wang, Juan Guo, Xiao Ren, Mingju Chao, Qiang Sun, Yu Jia and Erjun Liang.* Anomalous thermal expansion in Ta2WO8 oxide semiconductor over a wide temperature range. Inorganic Chemistry, 2021, 60, 17758−17764.

(22) Huanli Yuan, Qilong Gao*, Peng Xu, Juan Guo, Lunhua He, Andrea Sanson, Mingju Chao and Erjun Liang. Understanding negative thermal expansion of Zn2GeO4 through local structure and vibrational dynamics. Inorganic Chemistry, 2021, 60, 1499−1505.

(23) Yaxing Gao, Chunyan Wang, Qilong Gao,* Juan Guo, Mingju Chao, Yu Jia, and Erjun Liang*. Zero thermal expansion in Ta2Mo2O11 by compensation effects. Inorganic Chemistry, 2020, 59, 18427−18431

(24) Wei Wei, Qilong Gao*, Juan Guo, Mingju Chao, Lunhua He, Jun Chen and Erjun Liang*. Realizing isotropic negative thermal expansion covering room temperature by breaking the superstructure of ZrV2O7. Applied Physics Letters, 2020, 116, 181902.

(25) Qilong Gao, Jun Chen*, Qiang. Li, Ji. Zhang, Zhao. Zhai, Shantao. Zhang, Ranbo Yu and Xingran Xing. Structure and excellent visible light catalysis of Prussian blue analogues BiFe(CN)6×4H2O. Inorganic Chemistry Frontiers, 2018, 5, 438−445.

(26) Yixin Jiao, Qilong Gao*, Andrea Sanson, Erjun Liang, Qiang Sun*, and Jun Chen, Understanding Large Negative Thermal Expansion of NdFe(CN)6 through the Electronic Structure and Lattice Dynamics. Inorganic Chemistry, 2022, 61, 7813−7819

(27) Jiaqi Wang, Qilong Gao*, Andrea Sanson, Qiang Sun, and Erjun Liang*. Insight into the Relationship between Negative Thermal Expansion and Structure Flexibility: The Case of Zn(CN)2-Type Compounds. Inorganic Chemistry, 2022, 61, 34, 13239–13243.

(28) Yixin Jiao, Junzhe Liu, Qilong Gao*, and Qiang Sun*. Influence of A/B Element Substitution on Negative Thermal Expansion in AB(CN)6 (A = Al, Ga, In; B = Co, Fe, Mn, Cr, V, Ti): A Density Functional Theory Study. Inorg. Chem. 2023, 62, 35, 14291–14299

(29) Yi Zheng, Yixin Jiao, Yongqiang Qiao, Andrea Sanson, Juan Guo, Qiang Sun, Erjun Liang, and Qilong Gao*. Control of Thermal Expansion in TaVO5 by Double Chemical Substitution. Inorg. Chem. 2023, 62, 22, 8543–855

(30) Qilong Gao*, Yixin Jiao, Andrea Sanson, Erjun Liang, Qiang Sun*. Large negative thermal expansion in GdFe(CN)6 driven by unusual low-frequency modes. Chinese Chemical Letter, 2023, 34, 107564.

(31) Juan Guo, Mingyuan Fang, Qingsong Liu, Xiao Ren, Yongqiang Qiao, Mingju Chao, Erjun Liang, Qilong Gao*. Zero thermal expansion in Cs2W3O10. Chinese Chemical Letter. 2024, 35, 108957

(32) Jiaqi Wang, Qilong Gao*, Yaxing Gao, Yan Luo, Juan Guo, Qiang Sun and Erjun Liang. Uniaxial negative thermal expansion behavior of beta-CuSCN. Applied Physics Letters, 2021, 118, 222105.

(33) Qilong Gao*, YanLuo, Yongqiang Qiao, JuanGuo*, Erjun Liang Preparation, uniaxial negative thermal expansion and Raman study in semiconductor oxide Nb2WO8 ceramic. Ceramics International, 2022, 48, 34707-34712.

(34) Gaojie Zeng, Yaxing Gao, Juan Guo, Yongqiang Qiao, Erjun Liang*, Qilong Gao*. Negative thermal expansion in Co2-xMnxP2O7. Ceramics International, 2023, 49, 39843–39849

(35) Tongtong Hu, Yongqiang Qiao, Yameng Hu, Zifan Su, Jiaxin Guo, Xinwei Shi, Mingju Chao, Juan Guo*, Bin Wei*, Qilong Gao,*.Near-zero thermal expansion of GeNb18O47 ceramic. Ceramics International, 202450,15702-15708

(36) Hong Lian, Jiaqi Wang*, Bin Wei, Yueyang Yang, Yi Zheng, Juan Guo, Xinwei shi*, Erjun Liang, Qilong Gao*. Preparation and negative thermal expansion in medium-entropy ceramics (Zr1/3Hf1/3Ti1/3)V2O7. Ceramics International2024, 50, 18915-18922

(37) Qi Shao, Yongqiang Qiao, Xi Zhen, Juan Guo, Mingju Chao*, Erjun Liang, Qilong Gao*. Structure, phase transition, and tailoring thermal expansion in Cu2-xMnxP2O7. Ceramics International, 2023, 49, 27288–27293.

(38) JunzheLiu, YixinJiao, QilongGao*, QiangSun*, JunChen, Illuminating the negative thermal expansion mechanism of YFe(CN)6 via electronic structure and unusual phonon modes. Journal of Rare Earths, 2023, 41, 1258-1264.


(五)专利(已授权)

(1) 高其龙、高亚星,一种负热膨胀陶瓷Ta2W2O11及其固相烧结合成方法

(2)高其龙、张森、乔永强,一种负热膨胀材料CaSnF6及其制备方法

(3)高其龙、郑义、燕昱颖、刘俊杰,一种可调热膨胀系数材料Ta1-xTixMoxV1-xO5及其制备方法

(4)高其龙、郑义、刘俊杰、夏端阳,一种具有超宽温度下近零膨胀系数的陶瓷材料及其制备方法




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