邓亮 博士 研究员 课题组长
上海市零陵路 345 号， 中国科学院上海有机化学研究所， 200032
E-mail: deng@sioc.ac.cn
Group website: http://dengliang.sioc.ac.cn
基本信息：
出生年月： 1980年1月； 籍贯：湖南双峰
工作单位：中国科学院上海有机化学研究所
通讯地址：上海市零陵路345号， 200032
电话: 021-54925460， 13918692139
E-mail: deng@sioc.ac.cn
网页: http://dengliang.sioc.ac.cn
教育和工作经历：
2009/8 - 至今，中国科学院上海有机化学研究所，金属有机化学国家重点实验室，研究员
2007/1 - 2009/7，哈佛大学，化学与化学生物学系，博士后，导师： R. H. Holm 教授
2006/8 - 2006/12，香港中文大学，化学系，博士后，导师：谢作伟 教授
2002/8 - 2006/7，香港中文大学，化学系，博士，导师：谢作伟 教授
1998/9 - 2002/7，北京大学，化学与分子工程学院，学士，导师：席振峰 教授
荣誉和奖励：
国家杰出青年科学基金（2017）
美国化学会“Organometallics Young Investigator Fellows” (2014)
Thieme Chemistry Journals Award (2013)
国家优秀青年科学基金（2012）
上海市“浦江人才”计划（2011）
中国科学院“<>”计划（2010）
香港中文大学研究生最佳研究成果奖（2006）
北京大学“莙政”学者（2002）
北京大学光彩奖学金（2000）
学术团体任职：
《Organometallics》 副主编
《Organometallics》、《Inorganic Chemistry》 顾问编委,《中国化学快报》、《有机化学》 编委，
《中国化学》、《结构化学》 青年编委
中国化学会会员、 美国化学会会员、 上海市青年科技人才协会会员
研究方向:
过渡金属有机化学、 小分子活化、过渡金属催化。
通讯作者论文:
1. Liu, Yang; Cheng, Jun; Deng, Liang*, Three-Coordinate Formal Cobalt(0), Iron(0), and Manganese(0)
Complexes with Persistent Carbene and Alkene Ligation, Accounts of Chemical Research, 2020,
53(1), 244-254.
2. Du, Jingzhen; Chen, Wenwei; Chen, Qi; Leng, Xuebing; Meng, Yin-Shan; Gao, Song; Deng, Liang*,
Reactivity of a Two-Coordinate Cobalt(0) Cyclic (Alkyl)(amino)carbene Complex, Organometallics
2020, 39(5), 729-739.
3. Wang, Dongyang; Tamizmani, Masilamani; Leng, Xuebing; Deng, Liang*, Isolable Anion Radicals of
Nitrosoarenes, Chinese Journal of Chemistry, 2020, 38(2), 158-162.
4. Jun Cheng, Qi Chen, Xuebing Leng, Shengfa Ye,* Liang Deng*, Three-Coordinate Iron(0)
Complexes with N-Heterocyclic Carbene and Vinyltrimethylsilane Ligation: Synthesis,
Characterization, and Ligand Substitution Reactions, Inorganic Chemistry, 2019, 58(19),
13129-13141.
5. Dongyang Wang, Xuebing Leng, Shengfa Ye, Liang Deng*， Substrate Redox Non-innocence
Inducing Stepwise Oxidative Addition Reaction: Nitrosoarene C–N Bond Cleavage on
Low-Coordinate Cobalt(0) Species. Journal of the American Chemical Society, Journal of the
American Chemical Society, 2019,141(19), 7731-7735.
6. Jun Cheng, Jian Liu, Xuebing Leng, Thomas Lohmiller, Alexander Schnegg, Eckhard Bill, Shengfa
Ye,* Liang Deng*, A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis,
Characterization, and Its Diversified Reactivity of Nitrene Transfer and C-H Bond Activation.
Inorganic Chemistry, 2019, 58(11), 7634-7644.
7. Yafei Gao, Qi Chen, Xuebing Leng, Liang Deng*, Cyclometallation Reactions of a Three-Coordinate
Cobalt(I) Complex Bearing a Nonsymmetric N-Heterocyclic Carbene Ligand. Dalton Transaction,
2019, 48(26), 9676-9683.
8. Yin-Shan Meng, Zhenwu Ouyang, Mu-Wen Yang, Yi-Quan Zhang, Liang Deng*, Bing-Wu Wang*,
Song Gao*, Multiple Magnetic Relaxation Pathways in T-Shaped N-Heterocyclic Carbene-Supported
Fe(I) Single-Ion Magnets. Inorganic Chemistry Frontiers, 2019, 6, 1050-1057.
9. Jun Cheng, Qi Chen, Xuebing Leng, Zhongwen Ouyang, Zhenxing Wang*, Shengfa Ye*, Liang
Deng*, The Stabilization of Three-Coordinate Formal Mn(0) Complex with NHC and Alkene Ligation,
Chem, 2018, 4(12): 2844-2860.
10. Dongyang Wang, Qi Chen, Xuebing Leng, Liang Deng*, Reactions of Low-Coordinate
Cobalt(0)–N-Heterocyclic Carbene Complexes with Primary Aryl Phosphines. Inorganic Chemistry,
2018, 57(24): 15600-15609.
11. Qing Liu, Qi Chen, Xuebing Leng, Qing-Hai Deng*, Liang Deng*, Hafnium(II) Complexes with Cyclic
(Alkyl)(amino)carbene Ligation, Organometallics, 2018, 37(22): 4186-4188.
12. Peng Wang, Liang Deng*. Recent Advances in Iron-Catalyzed C-H Bond Amination via Iron Imido
Intermediate. Chinese Journal of Chemistry, 2018, 36(12): 1222-1240.
13. Yafei Gao, Liang Deng*, Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene
Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation,
1,2-Hydrosilylation, and Hydrogenation of Alkene, ACS Catalysis, 2018, 8(10): 9637–9646.
14. Jun Cheng, Lijun Wang, Peng Wang, Liang Deng*, High-Oxidation-State 3d Metal (Ti–Cu)
Complexes with N-Heterocyclic Carbene Ligation, Chemical Reviews, 2018, 118(19): 9930-9987.
(Invited Review)
15. Mingjing Zhao, Guoliang Mao*, Yang Liu, Jie Xiao, Liang Deng*. Synthesis, Structure, and
Nitrene-Transfer Reactivity of High-Spin Iron(II) Complex Featuring Iminoarsorane Ligation. Chinese
Journal of Organic Chemistry, 2018, 38(7): 1656-1662.
16. Yiming Fan, Jun Cheng, Yafei Gao, Min Shi*, Liang Deng*. Iron Dinitrogen Complexes Supported by
Tris(NHC)borate Ligand: Synthesis, Characterization, and Reactivity Study. Acta Chimica Sinica,
2018, 76(6): 445-452.
17. Yafei Gao, Guangyu Li, Liang Deng*, Bis(dinitrogen)cobalt(-1) Complexes with NHC Ligation:
Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on
Bound Diazene Complexes, Journal of the American Chemical Society, 2018, 140(6): 2239-2250.
18. Jian Sun, Yafei Gao, Liang Deng*, Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis,
Structure, and Their Reactions with Hydrosilanes, Inorganic Chemistry, 2017, 56(17): 10775-10784.
19. Zhenbo Mo, Liang Deng*, Open-shell iron hydrocarbyls, Coordination Chemistry Reviews, 2017, 350,
280-299. (Invited Review)
20. Yang Liu, Jingzhen Du, Liang Deng*, Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II)
Imido Complexes [(Me3P)3Co(NAr)], Inorganic Chemistry, 2017, 56(14): 8278-8286.
21. Jian Liu, Lianrui Hu, Lei Wang, Hui Chen*, Liang Deng*, An iron(II) ylide complex as a masked openshell iron alkylidene species in its alkylidene-transfer reactions with alkenes, Journal of the American
Chemical Society, 2017, 139(10): 3876-3888.
22. Jian Sun, Lun Luo, Yi Luo, Liang Deng*, An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition
of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes, Angewandte Chemie International Edition,
2017, 56(10): 2720-2724.
23. Yang Liu, Liang Deng*, Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of
Alkenes with Tertiary Silanes, Journal of the American Chemical Society, 2017, 139(5): 1798-1801.
24. Xiao-Nan Yao, Jing-Zhen Du, Yi-Quan Zhang, Xue-Bing Leng, Mu-Wen Yang, Shang-Da Jiang,
Zhen-Xing Wang, Zhong-Wen Ouyang, Liang Deng*, Bing-Wu Wang*, Song Gao*, Two-Coordinate
Co(II) Imido Complexes as Outstanding Single-Molecule Magnets, Journal of the American Chemical
Society, 2017, 139(1): 373-380.
25. Lijun Wang, Jun Cheng, Liang Deng*, A Square Planar Iron(II) Biphenyl-2,2'-diyl Complex with NHC
Ligation: Synthesis, Characterization, and its Reactivity toward Unsaturated Organic Substrates,
Inorganica Chimica Acta, 2017, 460, 49-54 (Invited paper for the special issue: Inorganic Chemistry -
The Next Generation).
26. Zhenwu Ouyang, Jun Cheng, Lingling Li, Xiaoli Bao, Liang Deng*, High-Spin Iron(I) and Iron(0)
Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands, Chemistry - A European
Journal, 2016, 22(40): 14162-14165.
27. Yafei Gao, Liang Deng*, Converting carbon dioxide into alkanes via alkane reverse combustion
reaction, Science Bulletin, 2016, 61(15): 1160-1162.
28. Liang Deng, Shuli You, Organometallics in Asia, Organometallics, 2016, 35(10): 1341-1342 (Editorial
for the special issue: Organometallics in Asia).
29. Zhenwu Ouyang, Yinshan Meng, Jun Cheng, Jie Xiao, Song Gao, Liang Deng*, Three- and
Four-Coordinate Homoleptic Iron(I)–NHC Complexes: Synthesis and Characterization,
Organometallics, 2016, 35(10): 1361-1367.
30. Yuesheng Liu, Lijun Wang, Liang Deng*, Selective Double Carbomagnesiation of Internal Alkynes
Catalyzed by Iron-N-Heterocyclic Carbene Complexes: A Convenient Method to Highly Substituted
1,3-Dienyl Magnesium Reagents, Journal of the American Chemical Society, 2016, 138(1): 112-115.
31. Jian Sun, Liang Deng*, Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes, ACS
Catalysis, 2016, 6(1): 290-300 (Invited Review).
32. Lei Wang, Lianrui Hu, Hezhong Zhang, Hui Chen*, Liang Deng*, Three-Coordinate Iron(IV) Bisimido
Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity, Journal of the
American Chemical Society, 2015, 137(44): 14196-14207.
33. Yin-Shan Meng, Zhenbo Mo, Bing-Wu Wang, Yi-Quan Zhang*, Liang Deng*, Song Gao*, Observation
of the single-ion magnet behavior of d8 ions on two-coordinate Co(I)-NHC complexes, Chemical
Science, 2015, 6(12): 7156-7162.
34. Jingzhen Du, Linbo Wang, Meihua Xie, Liang Deng*, A two-coordinate cobalt(II) imido complex with
NHC ligation: Synthesis, structure, and reactivity, Angewandte Chemie International Edition, 2015,
54(43): 12640-12644.
35. Yuesheng Liu, Lei Wang, Liang Deng*, Three-Coordinate Iron(II) Dialkenyl Compound with NHC
Ligation: Synthesis, Structure, and Reactivity, Organometallics, 2015, 34(17): 4401-4407.
36. Zhenwu Ouyang, Jingzhen Du, Lei Wang, Jared L. Kneebone, Michael L. Neidig, Liang Deng*, Linear
and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and
Structure Characterization, Inorganic Chemistry, 2015, 54(17): 8808-8816.
37. Xiaojie Wang, Jia Zhang, Lei Wang, Liang Deng*, High-Spin Iron(II) Alkynyl Complexes with
N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study, Organometallics,
2015, 34(12): 2775-2782.
38. Yuesheng Liu, Lun Luo, Jie Xiao, Lei Wang, You Song, Jingping Qu, Yi Luo*, Liang Deng*,
Four-Coordinate Iron(II) Diaryl Compounds with Monodentate N-Heterocyclic Carbene Ligation:
Synthesis, Characterization, and Their Tetrahedral-Square Planar Isomerization in Solution,
Inorganic Chemistry, 2015, 54(10): 4752-4760 (Cover paper).
39. Jian Sun, Chong Ou, Chao Wang*, M. Uchiyama, Liang Deng*, Silane-Functionalized N-Heterocyclic
Carbene-Cobalt Complexes Containing a Five-Coordinate Silicon with a Covalent Co-Si Bond,
Organometallics, 2015, 34(8): 1546-1551.
40. Yuesheng Liu, Jie Xiao, Lei Wang, You Song, Liang Deng* Carbon–Carbon Bond Formation
Reactivity of a Four-Coordinate NHC-Supported Iron(II) Phenyl Compound, Organometallics, 2015,
34(3): 599-605.
41. Hezhong Zhang, Zhenwu Ouyang, Yuesheng Liu, Qiang Zhang, Lei Wang, Deng Liang*,
(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: a Class of Valueable
Low-Coordinate Iron(0) Reagents, Angewandte Chemie International Edition, 2014, 53(32):
8432-8436.
42. Zhenbo Mo, Jie Xiao, Yafei Gao, Liang Deng*, Regio- and Stereoselective Hydrosilylation of Alkynes
Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes, Journal of the American
Chemical Society, 2014, 136(50): 17414-17417.
43. Long Zhang, Yuesheng Liu, Liang Deng*, Three-Coordinate Cobalt(IV) and Cobalt(V) Imido
Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity
in C-H Bond Amination, Journal of the American Chemical Society, 2014, 136(44): 15525-15528.
44. Yang Liu, Min Shi*, Liang Deng*, Iron(II) Dihydrocarbyls Supported by a Biphenyl-Linked
Bis(benzimidazol-2-ylidene) Ligand: Syntheses and Characterization, Organometallics, 2014, 33(20):
5660-5669 (Invited paper for the special issue: Catalytic and Organometallic Chemistry of
Earth-Abundant Metals).
45. Zhenbo Mo, Liang Deng*, Post-Functionalization: A Useful Method for the Synthesis of
Donor-Functionalized N-Heterocyclic Carbene-Transition-Metal Catalysts, Synlett, 2014, 25(08):
1045-1049 (invited review).
46. Zhenbo Mo, Zhenwu Ouyang, Lei Wang, K. L. Fillman, M. L. Neidig*, Liang Deng*, Two- and
Three-Coordinate Formal Iron(I) Compounds Featuring Monodentate Aminocarbene Ligands,
Organic Chemistry Frontiers, 2014, 1(9): 1040-1044.
47. Wansheng Zuo, Long Zhang, Meihua Xie*, Liang Deng*, Square Planar Nickel(II) Complexes with
Halogenated σ-Diiminobenzosemiquinonato Ligation: Synthesis, Characterization, and Redox
Property, Chinese Journal of Chemistry, 2013, 31(12): 1473-1482.
48. Zhenwu Ouyang, Liang Deng*, Iron(II) Complexes Featuring Bidentate N-Heterocyclic Carbene-Silyl
Ligands: Synthesis and Characterization, Organometallics, 2013, 32(24): 7268-7271.
49. Zhenbo Mo, Yang Liu, Liang Deng*, Anchoring of Silyl Donors on a N-Heterocyclic Carbene through
the Cobalt-Mediated Silylation of Benzylic C-H Bonds, Angewandte Chemie International Edition,
2013, 52(41): 10845-10849.
50. Long Zhang, Li Xiang, Yihua Yu, Liang Deng*, Reactivity of a Bis(amidinato)iron(II) Complex
[Fe(MesC(NPri)2)2] toward Some Oxidizing Reagents, Inorganic Chemistry, 2013, 52(10):
5906-5913.
51. Jie Xiao, Liang Deng*, Iron-mediated C-H bond amination by organic azides on a tripodal
bis(anilido)iminophosphorane platform, Dalton Transactions, 2013, 42(16): 5607-5610.
52. Xiaojie Wang, Zhenbo Mo, Jie Xiao, Liang Deng*, Monomeric Bis(anilido)iron(II) Complexes with
N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Redox Reactivity toward Aryl
Halides, Inorganic Chemistry, 2013, 52(1): 59-65.
53. Zhenbo Mo, Dake Chen, Xuebin Leng, Liang Deng*, Intramolecular C(sp3)-H Bond Activation
Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation, Organometallics, 2012,
31(20): 7040-7043.
54. Zhenbo Mo, Qiang Zhang, Liang Deng*, Dinuclear Iron Complex-Catalyzed Cross-Coupling of
Primary Alkyl Fluorides with Aryl Grignard Reagents, Organometallics, 2012, 31(18): 6518-6521.
55. Long Zhang, Liang Deng*, C-H bond amination by iron-imido/nitrene species, Chinese Science
Bulletin, 2012, 57(19): 2352-2360 (Invited review).
56. Qiang Zhang, Li Xiang, Liang Deng*, Dinuclear Iron-Imido Complexes with N-Heterocyclic Carbene
Ligation: Synthesis, Structure, and Redox Reactivity, Organometallics, 2012, 31(12): 4537-4543.
57. Jie Xiao, Liang Deng*, Synthesis, Structure, and Reactivity Study of Iron(II) Complexes with Bulky
Bis(anilido)thioether Ligation, Organometallics, 2012, 31(1): 428-434.
58. Zhenbo Mo, Yuxue Li, Hung Kay Lee, Liang Deng*, Square-Planar Cobalt Complexes with
Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Catalytic Application,
Organometallics, 2011, 30(17): 4687-4694.
59. Li Xiang, Jie Xiao, Liang Deng*, Synthesis, Structure, and Reactivity of Organo-Iron(II) Complexes
with N-Heterocyclic Carbene Ligation, Organometallics, 2011, 30(7): 2018-2025.
部分邀请报告:
 7th Razuvaev Lectures, Nizhny Novgorod, Russia, 16-21 September, 2019, Invited Lecture.
 The International Conference on Bioinspired Small Molecule Activation, Seoul, Korea, 6-9 June,
2019, Invited Lecture.
 The 10th National Conference of Inorganic Chemistry, Jinan, China, 18-21 August, 2019,
Keynote Lecture.
 International Conference on the Applications of the Mossbauer Effect (2019), Dalian, China, 1-6
September, 2019, Invited Lecture.
 The 12th International Symposium for Chinese Inorganic Chemists, Taipei, 26-29 October 2018,
Keynote Lecture
 Gordon Research Conference: Organometallic Chemistry, Newport, USA, 8-13 July 2018,
Invited Lecture
 The 43nd International Conference on Coordination Chemistry (ICCC-43), Japan, 30 July-4
August, 2018, Keynote Lecture
 The 6th Asian Conference on Coordination Chemistry (ACCC6), Melbourne, Australia, 23-28
July 2017, Keynote Lecture
 The 8th National Meeting on Coordination Chemistry, Dalian, China, 19 -22 July 2017, Keynote
Lecture
 The 5th Symposium on Advanced Biological Inorganic Chemistry, Kolkata, India, 7-11 January
2017, Invited Lecture
 International Symposium on Catalysis and Fine Chemicals 2016 (C&FC-2016), Taipei, 10-14
November 2016, Invited Lecture
 The 12th International Symposium on Organic Free Radicals, Shanghai, 9-14 October 2016,
Invited Lecture
 The 3rd International Conference on Organometallics and Catalysis, Seoul, Korea, 28-30 August
2016, Invited Lecture
 The 42nd International Conference on Coordination Chemistry (ICCC-42), Brest, France, 3 - 8
July 2016, Invited Lecture
 The 2nd Small Molecule Activation Conference, Cancun, Mexico, 20 - 23 May 2016, Invited
Lecture
 2015 SINO-Korea Bilateral Symposium on Coordination Chemistry, Xi’an, China, 17 -19
September 2015, Invited Lecture
 The 9th National Meeting on Inorganic Chemistry, Nanchang, China, 25 -29 July 2015, Invited
Lecture
 The 248th ACS National Meeting, San Francisco, USA, 10 - 14 August 2014, Invited Lecture
 The 18th National Meeting on Organometallic Chemistry, Lanzhou, China, 19 -22 August 2014,
Invited Lecture
 The 29th National Meeting of Chinese Chemical Society, Beijing, China, 3 -7 August 2014,
Invited Lecture
 The 41st International Conference on Coordination Chemistry (ICCC-41), Singapore, 21 - 25
July 2014, Invited Lecture
 Challenges in Inorganic and Materials Chemistry ISACS13, Dublin, Ireland, 1 - 4 July 2014,
Plenary Lecture
 The 1st International Symposium for Young Chemists on Stimuli-Responsive Chemical Species
for the Creation of Functional Molecules, Japan, Tokyo, 2 - 3 December 2013, Invited Lecture
 The 46th Heyrovský Discussion, Czech, Prague, 24- 25 June 2013, Invited Lecture
研究生培养:
 已培养博士11人：莫贞波、张龙、王小洁、刘月盛、王磊、欧阳振武、刘洋、孙键、高亚飞、 程骏、
王东阳
 已培养硕士8人： 叶伟、张河中、庞婷婷、左万胜（联培）、刘洋（联培）、王林波（联培）、 凡一明
（联培）、 赵明晶（联培）
研究合作者:
Prof. Gao Song, Peking University (magnetism)
Prof. You Song, Nanjing University (magnetism)
Prof. Yi Luo, Dalian University of Technology (theoretical calculation)
Prof. Hui Chen, Institute of Chemistry, CAS (theoretical calculation)
Prof. Bingwu Wang, Peking University (theoretical calculation)
Prof. Lili Zhao, Nanjing Tech University (theoretical calculation)
Prof. Michael Neidig, University of Rochester (MCD)
Prof. Shangda Jiang, Peking University (HYSCORE EPR)
Dr. Alexander Schnegg, Berlin Helmholtz Zentrum (FD-FT THz-EPR)
Prof. Zhenxing Wang, Huazhong University of Science and Technology (HF EPR)
Prof. Kyle Lancaster, Connell University (X-ray absorption spectroscopy)
Prof. Zheng Jiang, Shanghai Institute of Applied Physics, CAS (X-ray absorption spectroscopy)
Dr. Shengfa Ye, Max-Planck-Institut für Kohlenforschung (57Fe Mössbauer spectroscopy)
Dr. Eckhard Bill, Max-Planck-Institut für Kohlenforschung (57Fe Mössbauer spectroscopy)
Prof. Yisong Guo, Carnegie Melon University (NRVS)